Does anybody use org-roam to take notes on books?

Yes, org-roam-bibtex combined with org-ref is great. You can search your reference materials with using “meta data” you maintain in .bib file (BibTeX data, synced with Zotero, for instance) – see the screen shot below for org-ref screen.

I am assuming this is what you mean by “track key pieces of bibliographical data” and “access/search by metadata”?

You might find useful the discussion we have had recently, and my humble diagram that illustrates how these different applications work together.

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